Could Carly Pearce be gearing up to get married again? Who is Carly Pearce's Boyfriend? When Was Carly Pearce Married Before? The fact that Pearce has been ring shopping comes several years after her highly publicized marriage to fellow country singer Michael Ray. Top 20 Carly Pearce Songs From her heartbreaking ballads to messages about fun and faith, these are Carly Pearce's best 20 songs (so far).