The new season raises its curtain with a customary clash of European champions as Paris Saint-Germain take on Aston Villa. When is PSG vs Aston Villa? The Super Cup clash between PSG and Aston Villa kicks off at 8pm BST on Wednesday 12 August at the Red Bull Arena in Salzburg, Austria. Predicted line-upsAston Villa XI: Martinez; Cash, Konsa, Torres, Maatsen; Gomes, Kamara; Buendia, McGinn, Garnacho; Watkins. PSG XI: Safonov; Hakimi, Marquinhos, Pacho, Mendes; Beraldo, Neves, Vitinha, Zaire-Emery; Mbaye, Dembele, Kvaratskhelia.