And part of that is because villains are just so, so important to the very fabric of what makes a Spider-Man movie great. Perhaps you've heard that a new Spider-Man movie, titled Spider-Man: Brand New Day has recently been released. Without further ado, here's a complete ranking of every Spider-Man movie villain we've seen. No matter the case, he's a great, great, villain. Norman Osborn/Green Goblin (Willem Dafoe, Spider-Man 1, Spider-Man 2, Spider-Man 3)Sony PicturesHad to go with the king at the top of the list.