Pierce Brosnan and his wife Keely Shaye Smith are ultimate Hollywood couple goals, and even after more than three decades together, they appear just as loved-up as when they first met. Keely Shaye Smith and Pierce Brosnan attend the opening night of "Good Night, And Good Luck" in April 2025. Pic: FilmMagicFirst encounter in MexicoBefore they met, Pierce was married to actress and former Bond girl Cassandra Harris for 11 years, from 1980 until she tragically died in 1991 after a battle with ovarian cancer. He got a second chance at love when he met 30-year-old journalist Keely in Mexico in April 1994. Blended familyPic: Keely Brosnan/InstagramThe couple has two grown-up sons together who they welcomed before they got married.