FC Barcelona faces PSG in a UEFA Champions League game on Wednesday, Oct. 1, 2025 (10/1/25) at Estadi Olímpic Lluís Companys in Barcelona, Spain. Here’s what you need to know:What: UEFA Champions LeagueWho: Barcelona vs. PSGWhen: Wednesday, Oct. 1, 2025Time: 3 p.m. Whoever plays tomorrow is part of a real team,” Luis Enrique said Tuesday at a pre-match news conference. It is not a decisive game, so we are calm,” Luis Enrique said. Hansi Flick’s team was a Champions League semifinalist last season.