The aim of the study was to produce water-based polymer emulsions with hydrophobic properties by incorporating fluorinated and silane-containing monomers into the mini-emulsion polymerisation. Reading tip: Resins for Water-borne CoatingsExpand your knowledge and get fully acquainted with the various aspects of water-borne coatings – from production to properties to special features of their use! With the slow change from solvent-borne resins and coatings to water-borne coatings “Resins for waterborne coatings” is a must-read for any formulator wanting to expand their knowledge. Significantly improved hydrophobicity and thermal stabilityThe results show that the targeted modification with TFEMA and VTES significantly improves the hydrophobic properties, thermal stability and mechanical characteristics of the hybrid latexes. The use of sustainable raw materials in combination with functional monomers thus offers great potential for future water-based coating systems with targeted performance properties – particularly with regard to environmental friendliness and functionality.